PEEK or PAEK? What’s in a name?

John Grasmeder, Carin Burger

With the launch of new PAEKs (PolyArylEtherKetones) such as VICTREX AE™ 250 uni-directional tape for game-changing performance in aerospace composites and, more recently, VICTREX AM™ 200 filament which re-defines Z-direction strength in Additive Manufacturing, I’m frequently being asked “are these PEEK?” and “what’s the difference between PEEK and PAEK?”  Time for an explanation then!

The easiest way to think about this is to consider the term “PAEK” as the family name – it describes the general family of polymers which comprise as a minimum aryl, ether and ketone building blocks as I’ve mentioned in an earlier blog.

You might be surprised to know that there have been over 340 different PAEKs reported to date but most of these are amorphous and of little industrial interest.

The PAEK family: ~340 known polyarylrtherketones reported in the literature.

At Victrex, we prefer to focus on semi-crystalline materials, because this ensures polymers with good chemical resistance, fatigue, creep and wear properties, as I’ve discussed previously.

The best-known PAEK is PEEK, and its repeat unit looks like this:

Other PAEKs that Victrex manufactures include VICTREX HT™, which is PEK:

And VICTREX ST™, which is PEKEKK:

As the ratio of ketone-to-ether increases, so does the glass transition temperature (Tg) and the melting point (Tm).
A higher Tg can be desirable for applications requiring higher stiffness and strength at higher temperatures because this is the temperature above which the polymer changes from being stiff and glassy to being softer and more rubbery.

However, there’s a compromise here because a higher Tm means that the polymer must be processed at a higher temperature which can be challenging.  Typically, PAEKs are processed at temperatures 30 – 60°C above their Tm and realistically, it can become tricky to process thermoplastics much above 430°C.

Looking at the table above, there’s something really interesting going on:  I’ve included Tg and Tm measured on the Absolute or Kelvin temperature scale, K (in case you’re wondering, K = °C + 273.15).  When we look at the ratio of Tm-to-Tg based on the Kelvin scale, we can see that there is a constant ratio of 1.5 : 1 between them, and this is a kind of “unwritten rule” in what we call semi-crystalline all-para PAEKs.

Re-inventing the rules  
At Victrex, we asked ourselves, “wouldn’t it be great if we could break this rule?  Then we could lower the Tm without lowering the Tg, offering our customers a lower processing temperature whilst maintaining high temperature performance.”

This was the idea which ultimately led to the PAEKs we call LMPAEKs, used in VICTREX AE™ 250 UD tape and VICTREX AM™ 200 filament.  These polymers typically have a lower Tm:Tg ratio of 1.35, and that means a Tm and a processing temperature reduced by ~40°C but a Tg that is at least as good as PEEK’s.

In LMPAEK™ Explained and why it’s suited to composites and additive manufacturing we’ll explore some additional features and benefits of these unique VICTREX LMPAEK co-polymers which makes them ideally suited to composites, hybrid over-moulding and additive manufacturing.

© Victrex plc. 2021. All rights reserved.
Disclaimer


About the authors

John Grasmeder, Chief scientist at Victrex

Dr John Grasmeder has over 25 years’ experience in the polymer industry, in R&D, commercial and business leadership positions at ICI, BASF, Hoechst and Shell joint ventures in both the UK and Germany. He has been with Victrex since 2005 and was Technical Director from 2010. He became Chief Scientist in 2016.

LinkedIn

Carin Burger, Technical Service Engineer, Research & Development at Victrex

Carin Burger is a material scientist working at Victrex the past 14 years.  She has experience in R&D and technical services.  She enjoys her work as part of the EMEA technical service team, working with customers to solve their issues and providing support in design, processing and manufacturing.

LinkedIn

Hi, do you have PEEK questions I can help with?

Vic
Loading...